Would you like a post-Avengers solo move, an origin story or a mixture of both (batman begins style)??
Black Widow
Character » Black Widow appears in 3734 issues.
A former KGB agent, Natasha Alianovna Romanova, better known as Natasha Romanoff or Black Widow, was trained by the top-secret Soviet brainwashing and training program, the Red Room, to become the ultimate "Super-Spy". She defected from the Soviet Union to the US to join S.H.I.E.L.D. Subsequently, Black Widow proceeded to become a member of the Avengers and has been on the team on numerous occasions. She's a woman with an enigmatic past which very few are acquainted with.
Black Widow movie!
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